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硅油溶胀法一步制备高性能绝缘硅橡胶及其性能调控研究

One-Step Preparation of High-Performance Insulating Silicone Rubber via Silicone Oil Swelling Method and Its Performance Regulation Study

  • 摘要: 针对电力设备绝缘材料在复杂环境下疏水性衰减与介电性能难以协同提升的难题,本研究提出了一种基于二甲基硅油溶胀改性的硅橡胶性能调控新方法。通过将高温混炼硅橡胶在50 cSt硅油中溶胀处理(溶胀率106%),对其电学特性与机械性能进行了系统表征。测试结果表明:改性后材料介电常数为3.951,降低了6.5%;同时表面电阻率下降1个数量级,达到了4.32×1014Ω,而体积电阻率提升32%,形成了独特的“表面电荷耗散-本体绝缘增强”协同机制。据力学性能测试显示,拉伸强度为2.2 MPa,虽较对照组下降38.9%,但仍高于电力设备绝缘材料的力学阈值(1.5 MPa),且击穿强度保持率达99.8%。揭示了硅油分子对材料表/界面特性的差异化作用规律,对提升高湿重污地区电网外绝缘水平具有重要工程价值。

     

    Abstract: Aiming at the challenge of synergistic improvement between hydrophobicity decay and dielectric performance of electrical equipment insulating materials under complex environments, this study proposes a novel performance regulation method for silicone rubber based on dimethyl silicone oil swelling modification. By swelling high-temperature mixed silicone rubber in 50 cSt silicone oil (swelling ratio 106%), its electrical characteristics and mechanical properties were systematically characterized. Test results indicate that the dielectric constant of the modified material is 3.951, reduced by 6.5%; simultaneously, the surface resistivity decreases by one order of magnitude to 4.32×1014 Ω, while the volume resistivity increases by 32%, forming a unique "surface charge dissipation - bulk insulation enhancement" synergistic mechanism. Mechanical performance tests show a tensile strength of 2.2 MPa, although decreased by 38.9% compared to the control group, it still exceeds the mechanical threshold (1.5 MPa) for electrical equipment insulating materials, and the breakdown strength retention rate reaches 99.8%. The study reveals the differential action of silicone oil molecules on the material"s surface/interface characteristics, holding significant engineering value for improving the external insulation level of power grids in heavy humidity and pollution areas.

     

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