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换流变阀侧套管表带触指油浸状态腐蚀机理研究

Research on the Corrosion Mechanism of Strap Contact Fingers in Oil-immersed Condition for Converter Transformer Valve Side Bushings

  • 摘要: 针对特高压换流变阀侧套管表带触指在油浸环境下的腐蚀失效问题,通过现场拆解分析与模拟实验,揭示了其腐蚀机理及影响因素。对故障触指进行SEM、EDS、XRD表征及绝缘油成分检测,发现腐蚀产物以硫化亚铜(Cu2S)为主,且表面Ag含量随腐蚀程度加深从92.6%骤降至7.6%。结合高温腐蚀实验,表明温度与DBDS浓度协同加速腐蚀,250℃下仅3天即形成深黑色Cu2S层,腐蚀速率与DBDS浓度呈显著正相关。研究结果可为特高压设备可靠性提升与触指国产化提供了理论支撑。

     

    Abstract: This study investigates the corrosion-induced failure mechanism of spring finger contacts in valve-side bushings of ultra-high-voltage(UHV) converter transformers under oil-immersed conditions through on-site disassembly analysis and simulated experiments. Characterization techniques including SEM, EDS, and XRD were employed to analyze failed contacts, revealing copper sulfide(Cu2S) as the predominant corrosion product. Notably, the surface Ag content sharply decreased from 92.6% to 7.6% with increasing corrosion severity. Insulating oil composition analysis combined with high-temperature corrosion experiments demonstrated that elevated temperatures and dibenzyl disulfide(DBDS) concentration synergistically accelerate degradation. At 250 ℃, a dense Cu2S layer formed within merely 3 days, with corrosion rates exhibiting significant positive correlation with DBDS concentration. These findings provide critical theoretical foundations for enhancing UHV equipment reliability and advancing domestic manufacturing of corrosion-resistant spring finger contacts.

     

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