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钒电池旁路电流数学建模及分布特性研究

Study on Mathematical Modeling and Distribution Characteristics of Vanadium Battery Shunt Current

  • 摘要: 全钒液流电池储能系统因寿命长、安全性高、电池功率与储能容量相互独立等优点,被认为是最具有发展前景的储能系统之一。全钒液流电池电堆主要通过串联若干个单电池构成,全钒液流电池所需的电解液通过电解液总管并联分配到各单电池,电池之间的电解液管道是连通的,构成闭合回路,就会存在旁路电流,进而导致电荷损失、效率和容量利用率降低。介绍旁路电流的产生原理以及目前旁路电流的研究现状,再针对6个电池构成的电堆系统建立数学模型进行旁路电流分布计算。

     

    Abstract: Vanadium redox flow battery energy storage system is considered to be one of the most promising energy storage systems because of its long life, high safety, independent battery power and energy storage capacity. The whole vanadium redox flow battery stack is mainly composed of several single batteries in series. The electrolyte required by the whole vanadium redox flow battery is distributed in parallel to each single battery through the electrolyte main pipe. The electrolyte pipes between the batteries are connected, forming a closed loop, and there will be shunt current, resulting in charge loss, efficiency and capacity utilization reduction. This paper introduces the generation principle of shunt current and the present research status of shunt current. Then, the model of the six-battery stack system is built to calculate the shunt current distribution.

     

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